Abstract: 

Crystallization-driven self-assembly (CDSA) is a powerful approach for the solution self-assembly of block copolymers, enabling the formation of hierarchical nanostructures with high uniformity and structural precision. Unlike conventional solution self-assembly, where morphology is largely dictated by block composition, CDSA exploits crystallization of the core-forming block to favour low-curvature structures such as fibers and platelets and enables living growth processes.